How to determine half life by Theoretical Computational method?
Half life determination: Part 5
Determination of t1/2 ~ultra short or ultra high by Theoretical computation method
Theoretical computation of half life
There are several theoretical laws for the determination of half life of a radioisotopes. Geiger-Nuttall
law is oldest among them, which is an empirical law for the determination of half lives of alpha
particle emitters. [Geiger, H., (1911) et al] using the following equation
where λ is the decay constant (λ = ln2/half-life), Z the atomic number, E the total kinetic energy (of the alpha particle and the daughter nucleus), and a1 and a2 are constants.
Apart from this half life can be computed by using Universal decay law (UDL) from R-matrix theory [Akrawy, D. T., (2019) et al.], Semifission formula [Poenaru, D. N., (2006) et al] etc. Theoretical estimation have profound application is super heavy radionuclides, where experimental half life measurements are yet to be carried out as well as for the radioisotopes with very very long half lives e.g. 124Xe (1.8 x 10^22y), 128Te (2.41×10^24 yr), 209Bi (4.6 x 10^19). It is often claimed that the calculated half-life values are is in agreement with the experimental data. Theoretically calculated half lives often in good agreement with measured results e.g. theoretical prediction of 209Bi’s half life was 4.6 x 10^19 y which is in good agreement with obtained result 1.9 (± 0.2) x 10^19y [Dumé, B. (2007)].
Advantage
Minimum or no experiment
Very useful for extreme cases e.g. very low or very high half lives
Disadvantage
Predictive in nature
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